Molecular and Crystal Structure of Hexacobalt Carbonyl Cluster Containg Twin Co_3S(CO)_7 Fragments L

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:eaglesword
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Reaction of dimers of (R) thionophosphine sulfide (R = P - C6H4OMe,SMe ) with Co, (CO), yields the novel hexacobalt cluster [Co’(μ3, -S)2, (CO) 14 (μ4 -μ4- and the trinuclear clusterPSCH,)J 2’ In 1, tw0 Co3S(C0)7 units linked by a novel phosphido-thio1ato bifunc-tiona1 bridging p’-SPR ligand as backbone. Reaction of dimers of (R) thionophosphine sulfide (R = P - C6H4OMe, SMe) with Co, (CO), yields the novel hexacobalt cluster [Co ’ and the trinuclear cluster PSCH, J 2 ’In 1, tw0 Co3S (C0) 7 units linked by a novel phosphido-thio1ato bifunc tion1 bridging p’-SPR ligand as backbone.
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