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采用内禀反应坐标法完成了对甲基叠氮热解反应途径的微观动力学解析.结果表明甲基叠氮的热解是以伴随N_2消除后发生1,2-H迁移的协同方式完成的,属协同的非同步反应,此机制可解释(H_3C)nH_(3-n)C—N_3(n=0～2)烷基叠氮系列热解温度的光电子能谱结果.
The intrinsic kinetic coordinate method was used to accomplish the micro-kinetic analysis of the pyrolysis reaction of methyl azide. The results show that the pyrolysis of methyl azide is accomplished in a synergistic manner with the 1,2-H migration accompanying the elimination of N 2 , Which is a synergistic asynchronous reaction. This mechanism can explain the photoelectron spectroscopy results of pyrolysis temperature of (H_3C) nH_ (3-n) C_N_3 (n = 0 ~ 2) alkyl azide series.