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The structure of the complex [Co(PMBP-tsc) 2·2DMF·2H 2O] (PMBP-tsc=1-phenyl-3-methyl-4-benzoylpyrazol-5-one-thio~se~mi~car~bazone) has been determined by X-ray crystallography. It crystallizes in the orthorhombic system, space group Pna2 1, with lattice parameters a=2.1170(3) nm, b=1.2780(10) nm, c=1.8956(2) nm, V=4.5258(9) nm 3 and Z=4. The structure shows that Co 2+ in the complex is hexa-coordinated with a distorted octahedral coordination sphere. The water molecules bridge the adjacent stacks through hydrogen bonds and lead to supramolecular formation with three-dimensional network structure.
The structure of the complex [Co (PMBP-tsc) 2 · 2DMF · 2H 2O] (PMBP-tsc = 1-phenyl-3-methyl-4-benzoylpyrazol-5-one-thio ~ se ~ mi ~ car ~ bazone) It has been determined by X-ray crystallography. It crystallizes in the orthorhombic system space group Pna2 1 with lattice parameters a = 2.1170 (3) nm, b = 1.2780 (10) nm, c = 1.8956 The water molecules bridge the adjacent stacks through hydrogen bonds and lead to supramolecular formation with three- dimensional network structure.