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本文合成了四种新配合物:二氯化双苯甲醛缩氮基硫脲合铜(Ⅱ)(Cu~Ⅱ(Betsc—H)_2Cl_2),三氯化水杨醛缩氨基硫脲合铁(Ⅲ)(Fe~Ⅲ(Satsc—H_2)Cl_3,二氯化双对二甲氨基苯甲醛缩氨基硫脲合钴(Ⅱ)(Co~Ⅱ(Dmabtsc—H)_2Cl_2·H_2O)及双对硝基苯甲醛缩氨基硫脲合钴(Ⅱ)醋酸盐(Co~Ⅱ(Nitsc—H)(Nitsc)(Ac))。用元素分析和IR测定了化合物的组成,并进行了吸放O_2和CO的试验。
In this paper, four novel complexes were synthesized: bis (benzaldehyde) bis (benzothiadiazolyl) thiourea copper (Ⅱ) (Cu ~ Ⅱ (Betsc-H) (Ⅱ) (Co ~ Ⅱ (Dmabtsc-H) 2 Cl 2 · H 2 O) and bis-p-nitro The composition of the compound was determined by elemental analysis and IR, and the adsorption and desorption of O_2 and CO (N) were also studied. Test.