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氮配位过渡金属配合物在近十几年来得到迅速的发展。通过设计不同的含氮配体与不同过渡金属进行配位形成的氮配位过渡金属配合物,在硅氢加成反应中有很大应用研究价值。本文综述了氮配位铑、铁、铼、钴、锌等过渡金属配合物在酮或者烯烃的硅氢加成反应中的新进展。二唑啉及二氢吡咯等含氮配体的优化设计必将大大促进含氮铁、铼、钴配合物在酮或者亚胺的硅氢加成反应中的应用。
Nitrogen coordination transition metal complexes in the past decade has been rapid development. Through the design of different nitrogen-containing ligands and different transition metal coordination formation of nitrogen coordination transition metal complexes, hydrosilylation reaction has great application research value. In this paper, new progress in the hydrosilylation reaction of transition metal complexes of rhodium, iron, rhenium, cobalt, zinc with ketones or olefins is reviewed. The optimized design of nitrogenous ligands such as dioxazoline and dihydropyrrole will greatly promote the application of nitrogenous iron, rhenium and cobalt complexes in the hydrosilylation reaction of ketones or imines.