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一、引言 CoX_3L_N~+(X=Cl,Br,I,L_N~+=monoprotorated 1-methly piperazine)配合物属阳离子与过渡金属离子配位的配合物。Quagliano等人首先研究了阳离子配体与过渡金属配位的配合物。对CoX_3L_N~+配合物,Marcotrigiano测出了它的光谱和磁矩;Carrett等在C_3,对称晶场下(忽略组态相互作用)定性地指定了CoBr_3L_N~+的光谱。Marcotrigiano估计了配合物CoX_3L_N~+在L_N~+影响下的畸变特性,配体的配位能力及正电荷效应。得出了
I. INTRODUCTION CoX_3L_N ~ + (X = Cl, Br, I, L_N ~ + = monoprotorated 1-methly piperazine) complex is a complex of cation and transition metal ion. Quagliano et al first studied the coordination of cationic ligands with transition metal complexes. For CoX_3L_N ~ + complexes, Marcotrigiano measured its spectrum and magnetic moment; Carrett et al. Assigned the spectrum of CoBr_3L_N ~ + qualitatively under the C_3 symmetry crystal field (ignoring the configuration interaction). Marcotrigiano estimated the distortion properties of the complex CoX_3L_N ~ + under the influence of L_N ~ +, the ligand coordination ability and the positive charge effect. Got it