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A novel POSS-based organic/inorganic hybrid covalently attached at molecular level,2-(4-(allyloxy)phenyl)-5-(4-(octylox- y)phenyl)-1,3,4-oxadiazole-POSS(6)(abbreviated as oxadiazole-POSS)was synthesized by Pt(dcp)catalyst.The hybrid was soluble in common organic solvents such as CHCl_3,toluene,C_2H_4Cl_2,and THF.Its structures and properties were characterized and evaluated with FTIR,~1H NMR,~(13)C NMR,~(29)Si NMR,EA,TGA,DSC,GPC,and CV,respectively.The results show that the novel hybrid possesses high thermal stability and good electron injection ability.
A novel POSS-based organic / inorganic hybrid covalently attached at a molecular level of 2- (4- (allyloxy) phenyl) -5- (4- (octylox- y) phenyl) -1,3,4-oxadiazole-POSS (abbreviated as oxadiazole-POSS) was synthesized by Pt (dcp) catalyst. The hybrid was soluble in common organic solvents such as CHCl 3, toluene, C 2 H 4 Cl 2, and THF.Its structures and properties were characterized and evaluated with FTIR, ~ 1H NMR , ~ (13) C NMR, ~ (29) Si NMR, EA, TGA, DSC, GPC, and CV, respectively. These results show that the novel hybrid possesses high thermal stability and good electron injection ability.