论文部分内容阅读
研究了用紫外激光（355nm）诱导C60与金属羰基化合物M（CO）6（M＝Cr；Mo，W）的配位反应，合成了具有C4υ对称性的配位络合物（η2－C60）M（CO）5，并初步讨论了C60与M（CO）6反应的动力学过程．
The coordination reaction between C60 and metal carbonyl M (CO) 6 (M = Cr; Mo, W) was induced by UV laser (355 nm), and the coordination complex (η2- M (CO) 5. The kinetics of the reaction between C60 and M (CO) 6 was also discussed.