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研究有机银离子导体[(CH_3)_4N]_2Ag_(13)I_(15)的制备工艺以及结构对电性能和稳定性的影响。发现 AgI 中加入适量的(CH_3)_4NI 后,通过特殊的热处理工艺,使体心立方结构的α—AgI 变为具有变形的β—Mn 复杂立方结构,从而获得在室温下电导率为4.1×10~(-2)(Ω·cm)~(-1)的有机银离子导体。
The preparation of organic silver ion conductor [(CH_3) _4N] _2Ag_ (13) I_ (15) and the effect of structure on electrical properties and stability were studied. After adding appropriate amount of (CH_3) _4NI into AgI, the α-AgI of the body-centered cubic structure was changed to a deformed β-Mn complex cubic structure through a special heat treatment process, and the conductivity at room temperature was 4.1 × 10 ~ (-2) (Ω · cm) -1 organic silver ion conductor.