,Supercooled liquids analogous fractional Stokes–Einstein relation in NaCl solution above room tempe

来源 :中国物理B(英文版) | 被引量 : 0次 | 上传用户:glx19891006
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The Stokes–Einstein relation D~T/ηand its two variants D~τ?1 and D~T/τfollow a fractional form in super-cooled liquids, where D is the diffusion constant, T the temperature,η the shear viscosity, andτ the structural relaxation time. The fractional Stokes–Einstein relation is proposed to result from the dynamic heterogeneity of supercooled liquids. In this work, by performing molecular dynamics simulations, we show that the analogous fractional form also exists in sodium chloride (NaCl) solutions above room temperature. D~τ?1 takes a fractional form within 300–800 K;a crossover is observed in both D~T/τ and D~T/η. Both D~T/τ and D~T/η are valid below the crossover temperature Tx , but take a fractional form for T >Tx . Our results indicate that the fractional Stokes–Einstein relation not only exists in supercooled liquids but also exists in NaCl solutions at high enough temperatures far away from the glass transition point. We propose that D~T/η and its two variants should be critically evaluated to test the validity of the Stokes–Einstein relation.
其他文献
苹果(Malus domesticaBorkh)是人们经常食用的水果之一,在世界范围内广泛种植。但是,苹果受到干旱及高盐等逆境的胁迫限制了苹果的产量及品质。研究表明,碱性亮氨酸拉链(bZIP)蛋白具
随着基础教育改革向纵深推进,人们已逐渐认识到了课外阅读在小学语文学习过程中的重要意义.因此,在当前的小学语文教学中应重视小学生课外阅读指导.
We demonstrate a high performance GaAs/AlGaAs-based quantum-well photodetector (QWP) device with a peak response frequency of 4.3 THz.The negative differential
关于的教学设计:课件引入,揭示课题;初读课文,把握整体;文本对话,走近胡杨;回归全文,升华主题.本文从以上方面对一文进行详细解读.
In order to clarify the influence of methane concentration and deposition time on self-organized nano-multilayers,three serial copper-carbon films have been pre
提高初中信息技术课堂效率,必须真正实施师生互动模式,努力培养学生的学习兴趣、操作能力、感悟水平和创新思维意识.
语文是人的精神家园,学生语文素养的形成很大程度上取决于在学习在过程中受到的精神滋养.语文教育的真正价值就在于引领学生获取这种感受,体验这种情感,获取这种智慧,积淀这
番木瓜(Carica papaya L.)原产美洲热带,是一种热带亚热带速生双子叶、多性别多年生常绿果树,基因组较小(2n=18),为我国南方名优水果,是岭南佳果之一。17世纪传入我国,栽培历史已
要不要拓展,如何选取拓展资源,以及怎样进行拓展,这些问题无一不是每一个语文教师教学实践中所面临的问题,也无一不是对教师教学智慧的巨大考验.只有我们潜心研究,探索,才能
期刊
The propagation dynamics of a chirped Airy vortex (CAiV) beam with x-polarization in uniaxial crystals orthogonal to the optical axis is studied analytically an