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本文用循环伏安法研究镥单酞菁和镥双酞菁在非水溶剂中的电化学行为,获得了相应的氧化还原反应半波电位E1/2,测定了其中四个氧化还原反应的电子转移速度常数ks。指出非水溶剂对镥单酞菁和镥双酞菁的电化学行为具有程度不同的影响。
In this paper, cyclic voltammetry was used to study the electrochemical behavior of phthalocyanine and phthalocyanine in non-aqueous solvents. The corresponding half-wave potentials E1 / 2 of the redox reaction were obtained. Among them, four redox reactions Transfer rate constant ks. It is pointed out that the non-aqueous solvents have different degrees of influence on the electrochemical behavior of 镥monophthalocyanine and 镥-bisphthalocyanine.