SPHERULITIC STRUCTURE AND MORPHOLOGY OF POLY(ETHYLENE SUCCINATE)/POLY(ETHYLENE OXIDE) (PES/PEO) BLEN

来源 :高分子科学(英文版) | 被引量 : 0次 | 上传用户:liudongjiw
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The spherlitic structure and morphology development of poly(ethylene succinate)/poly(ethylene oxide) (PES/PEO) blends with one-step crystallization behavior were observed by means of polarizing optical microscope.It was found that the pure PES spherulite in which the adequate quantity of PEO melt existed in the interlamellar regions,and the blending spherulite formed by both PES and PEO lamellae could form simultaneously.When the two types of spherulites contacted with each other the front of the blending spherulite could penetrate into the pure PES spherulite to grow continually.This penetration growth behavior was also observed when the mini-crystal particles of the PES component were formed at lower crystallization temperatures.The kinetics analysis showed that the penetration growth rate was faster than that in the original melt.It was evidenced that the increasing of growth rate and the formation of new growth site should be the typical characteristics of interpenetrated growth in binary crystalline polymer blends.
其他文献
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7
We present a general framework for a higher-order spline level-set (HLS) method and apply this to biomolecule surfaces construction. Starting from a first order
A high molecular weight (Mw=1.85×107) polystyrene (PS) with narrow distribution was prepared by high vacuum anionic polymerization in tetrahydrofuran.By use of
The thermal decomposition of ammonium 3-nitro-1,2,4-triazol-5-onate monohydrate[NH4(NTO).H2O] wasstudied by means of thermal analysis-MS coupling and the combin
Three fluorescent indocyanines containing p-carboxybenzyl groups on N atoms in the heterocyclic rings were synthesized under supersonic. The maxima wavelength o
Precursor decomposition was used for the preparation of VTeO/SBA-15 catalyst for the selective oxidation of propane to acrolein.The catalyst shows a better perf
Two master-batches,polyamide 66 (PA66)/organo-montmorillonite (OMMT) and polyamide 6 (PA6)/OMMT,prepared by melt compounding with methyl methacrylate (MMA) as c
[CoII(phen)3]2[{(ZnW12O40)CoII(phen)2(H2O)}2CoII(trien)2(NaH20)2]·3H2O was synthesized via hydrothermal technique and characterized with elemental analyses,IR
The typical immiscible PP/PS blend based clay nanocomposites were prepared via melt blending.The dispersion of clay was determined by X-ray diffraction (XRD) an
Coupled extensional and flexural cylindrical vibrations of a corrugated cylindrical piezoelectric shell consisting of multiple pieces of circular cylindrical su