一、引言在1938—1946年这段时间,Oxo反应的开发者,Roelen通过改进F-T合成,得到终产物醛和酮。从此实现了α-烯烃、CO、H_2为原料的氢甲酰化反应。随着钴系、铑系络合催化剂的工业开发,寻找新的络合催化体系的研究,一直受到重视。七十年代后期,铂系络合物的研究有了新的进展。 I. INTRODUCTION During 1938-1946, Roelen, the developer of the Oxo reaction, obtained the final aldehydes and ketones by improving F-T synthesis. Since then, the hydroformylation of α-olefin, CO and H 2 has been achieved. With the industrial development of cobalt-based and rhodium-based complex catalysts, the search for new complex catalyst systems has drawn great attention. In the late seventies, platinum alloy complexes have made new progress.