论文部分内容阅读
Photofunctional materials with room-temperature phosphorescence(RTP)commonly appeared in expensive metal-coordination complexes and rare-earth-based compounds.Recently,the metal-free organic RTP materials have been paid growing attention from scientific community because of the ease of molecular design,low cost as well as potential applications in molecular switches,chemical sensors and biological imaging.To date,efficient RTP materials with high quantum yield are still very limited due to the T_1-S_0 spinforbidden process and weak spin-orbital coupling.Current mechanism based on crystallization-induced or aggregationinduced phosphorescence may serve as an effective way to enhance the RTP[1,2];however a large quantity of crystals
Photofunctional materials with room-temperature phosphorescence (RTP) have appeared in expensive metal-coordination complexes and rare-earth-based compounds. Recently, the metal-free organic RTP materials have been paid growing attention from scientific community because of the ease of molecular design , low cost as well as potential applications in molecular switches, chemical sensors and biological imaging. To date, efficient RTP materials with high quantum yield are still very limited due to the T_1-S_0 spinforbidden process and weak spin-orbital coupling. Current mechanism based on crystallization-induced or aggregationinduced phosphorescence may serve as an effective way to enhance the RTP [1,2]; however a large quantity of crystals