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The reaction of Co~II ions with 1,4-bis(imidazol)butane(bimb) or 1,4-bis(triazol)butane(bitb) in the presence of ClO_4~-, respectively affords two CoII coordination complexes, namely {[Co(bimb)_3]·2ClO_4}n(I) and {[Co(bitb)_3]·2ClO_4}n(II). Single-crystal X-ray analysis indicates that both complexes I and II show the same α-Po topological structures. However, complex I exhibits a 2-fold interpenetrating network, while complex II features a 3-fold interpenetrating network. In addition, solid-state properties such as thermal stabilities and magnetic properties of two complexes were also investigated.
The reaction of Co ~ II ions with 1,4-bis (imidazol) butane (bimb) or 1,4-bis (triazol) butane (bitb) in the presence of ClO 4 ~, respectively affords two CoII coordination complexes, namely Single-crystal X-ray analysis indicates that both complexes I and II show the same α- [Co (bimb) _3] .2ClO_4} n (I) and {[Co (bitb) _3] .2ClO_4} n However, complex I exhibits a 2-fold interpenetrating network, while complex II features a 3-fold interpenetrating network. In addition, solid-state properties such as thermal stabilities and magnetic properties of two complexes were also investigated.