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A new coordination polyme[Co (imbz)2(H2O)2]n[imbz =4’-(imidazol-1-ylmethyl)benzoate anion]was synthesized and characterized b y x-ray crystallography.The title c omplex crystallizes in monoclinic,space group P21/c,a=10.910(2),b=8.8720(18),c=11.252(2)?,β=92.20(3)°,V=1088.3(4)?3,Z =2,Dc=1.518g·cm-3,μ=0.836cm -1,F(000)=514,R=0.0679,w R=0.1710.Each Co ?atom has a distorted octahedral coordination geometry and is six-coord-inated by two water molecules and fou r imbz ligands.Each imbz ligand connects two Co ?to gen-erate an infinite 1D twisted chain structure.
A new coordination polyme [Co (imbz) 2 (H2O) 2] n [imbz = 4’- (imidazol- 1-ylmethyl) benzoate anion] was synthesized and characterized by x-ray crystallography.The title c omplex crystallizes in monoclinic, Space group P21 / c, a = 10.910 (2), b = 8.8720 (18), c = 11.252 (2) ?, β = 92.20 (3) °, V = 1088.3 = 1.518 g · cm -3, μ = 0.836 cm -1, F (000) = 514, R = 0.0679, w R = 0.1710. Since Co? Atom has a distorted octahedral coordination geometry and is six-coord-inated by two water molecules and fou r imbz ligands. Each imbz ligand connects two Co? to gen-erate an infinite 1D twisted chain structure.