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硼氢化合物和铁氰化物反应生成硼酸盐和亚铁氰化物已经在缓冲水溶液中被研究过。发现在硼氢化合物和氢离子两者中铁氰离子消失的速率是一级反应,且不依赖于铁氰酸离子,它有一个正常的双分子频率因数为5.9×10~(11)秒~(-1),活化能为7.2仟卡。所提出的机构是和硼
The reaction of borohydrides with ferricyanide to form borates and ferrocyanides has been studied in aqueous buffered solutions. It was found that the rate of disappearance of ferricyanide in both the borohydride and the hydrogen ions is a first order reaction and is independent of the ferricyanide ion and it has a normal bimolecular frequency factor of 5.9 x 10-11 seconds to -1), activation energy of 7.2 thousand cards. The proposed mechanism is with boron