本文在介绍了混合价态络合物的类型,络合物中电子迁移过程的能量因素与荷移谱带关系的基础上,结合各种实验数据从理论上着重讨论了络合物中的电子状态,桥联配体的性质对电子迁移、电子状态的影响,以及该类络合物中的电子迁移机理。同时提出电子迁移采取外圈机理的假定,给出外圈反应机理的一般模型。 In this paper, based on the introduction of the types of mixed valence complexes, the relationship between the energy factors and the charge-transfer bands in the electron transport process of the complexes, and in combination with various experimental data, State, the nature of bridged ligands on the electron transfer, the electronic state, and the electron transport mechanism in this type of complex. At the same time, the assumption that the electron transfer takes the outer ring mechanism is proposed and the general model of the outer ring reaction mechanism is given.