Preparation and Characterization of Nanosized CeO_2/γ-Al_2O_3 Composite Supports

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:purple601
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Based on the γ-Al2O3 support with large-size pores, impregnation-deposition method was adopted to prepare the nano CeO_2/γ-Al2O3 composite supports. The results of XRD showed that there was no CeO_2-Al2O3 mixture or solid solution, indicating that CeO_2 was only loaded on the surface of Al2O3. The CeO_2/γ-Al2O3 composite support had larger specific surface area (170 m2·g-1), while for the non-loaded nanosized CeO_2, the specific surface area was small(~50 m2·g-1). The influence of impregnation and drying methods on the surface properties, thermal stability and crystal structure of composite supports was characterized by XRD, DTA and BET. The CeO_2/γ-Al2O3 composite support prepared by vacuum impregnation and microwave drying was better than that prepared by conventional impregnation and drying. Based on the γ-Al2O3 support with large-size pores, impregnation-deposition method was prepared to nano-TiO2 / γ-Al2O3 composite supports. The results of XRD showed that there was no CeO_2-Al2O3 mixture or solid solution, indicating that CeO 2 was only loaded on the surface of Al 2 O 3. The CeO 2 / γ-Al 2 O 3 composite support had larger specific surface area (170 m2 · g -1), while for the non-loaded nanosized CeO 2, the specific surface area was small m2 · g-1). The influence of impregnation and drying methods on the surface properties, thermal stability and crystal structure of composite supports was characterized by XRD, DTA and BET. The CeO2 / γ-Al2O3 composite support prepared by vacuum impregnation and microwave drying was better than that prepared by conventional impregnation and drying.
其他文献
1998年机构改革以来 ,中央国家机关后勤部门按照《关于深化国务院各部门机关后勤体制改革的意见》 (国办发 [1998]147号 )的精神 ,以实现机关后勤管理科学化、保障法制化、服
群众监督是最基本、最重要的监督形式,它的基础地位一方面是由中国共产党的宗旨和“三个代表”的要求所决定的,另一方面是由人民群众当家作主的地位和在反腐败斗争中的主体地位
An infrared integration method to discover the object of high temperature in the video image is put forward by analyzing not only the radiation spectrum distri
Using transfer matrix method, the optical transmission properties in one-dimensional (1-D) photonic crystal is analyzed. When the temperature varies, not only t
《下下星期五》(Next Friday)的故事发生在《星期五》故事的3年后的一个星期五。三年前困扰着克雷格的街区恶棍终于从监狱里面放出来了,而且发誓要报复克雷格。忧心忡忡的父
华纳兄弟影片公司导演:斯蒂文·索德伯格主演.乔治-克鲁尼.布拉德·皮特.马特-达蒙,朱丽娅。罗伯茨、安迪·嘉西亚、唐·奇德尔等 斯蒂文‘索德伯格谈到他的全明星阵容的盗贼
将一片真情融入所爱的建筑事业中——记四川省化工建设总公司一级项目经理汤海波汤海波同志,四川省化工建设总公司员工,先后毕业于四川省泸州化工学校化工仪表及自动化专业和
随着2017年高考数学考试大纲中增加了对数学文化的考查,各地模考试题中数学文化试题像雨后春笋般涌现出来,笔者现采撷一些立体几何文化试题,进行赏析.例1(2017届河北省定州中
职务犯罪是国家工作人员利用职务之便而触犯刑律的犯罪行为。作为新时期反腐败斗争的一项治本之策,预防职务犯罪、查处职务犯罪已越来越受到各级党政和纪检、检察部门的高度重
当电影不再神秘……随着社会的发展,科技的进步,资讯的发达,现在感到神秘的事情则越来越少。过去在人们印象中许多高深莫测、高不可攀的事情已逐渐拂去了神秘的面纱,走出了