Catalytic Oxidation of NO over La0.8Sr0.2MnO3 Perovskite

来源 :高等学校化学研究(英文版) | 被引量 : 0次 | 上传用户:lhawk
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Catalytic oxidation of NO by O2 over La0.8Sr0.2MnO3 was tested in a tubular reactor.The reaction temperature ranged from 373 to 473 K,space time from 0.090 to 0.720 s,inlet NO concentration from 300 to 2000 μL/L,and O2 volume fraction from 3% to 9%.The steady-state conversion of NO was increased significantly with increasing reaction temperature and the space time,slightly with increasing the O2 concentration but decreased with increasing the inlet NO concentration at a lower temperature.Under the conditions of 0.720 s space time,500 μL/L NO concentration,5% O2 volume fraction and 473 K,NO conversion reached 90%.A kinetic model including a network of 12 elementary reactions with the desorption of NO2 as the rate-limiting step is established and fits the experimental data well.The activation energy of NO2 desorption from the catalyst surface is determined to be 101 kJ/mol.
其他文献
本文通过对荣华二采区10
In this paper,a result on the persistence of lowner dimensional invariant tori in Cd reversible systems is obtained under some conditions.The theorem is proved
Soil heat flux is important for surface energy balance (SEB),and inaccurate estimation of soil heat flux often leads to surface energy imbalance. In this paper,
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7
The new title compound N-(5-(4-chloro-2-(trifluoromethyl)phenyl)furan-2-carbon-yl)- N'-(4,6-dimethylpyrimidin-2-yl)thiourea (C19H14ClF3N4O2S) has been synthesiz
Split Hopkinson pressure bar (SHPB) technique is used to determine the dynamic strength of reactive powder concretes (RPCs) with different steel-fiber contents.
A chemoreduction-purge-and-trap gas chromatographic method has been developed for the determination of trace dimethylsulfoxide (DMSO) in seawater.In the analysi
The asymmetric inlet velocity profile has been observed in phantom model using LDA and in health subjects using Magnet Resonance (MR). The effects of asymmetric
The effect of loading rate on the dynamic fracture properties and the failure mechanisms of glass fiber-reinforced composite materials under mode I fracture is
Two novel biscrown ethers with rigid cisltrans ethylene linker were synthesized v/a Wittig reaction in high yield (about 80%).Their pure cis/trans-isomers were