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A new Zn(Ⅱ) complex,[Zn(1,2,3-HBTC)(L)]2(1,L = 2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,2,3-H3 BTC = 1,2,3-benzentricarboxylic acid),was synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction.It crystallizes in triclinic,space group P1 with a = 10.455(2),b = 11.533(2),c = 12.499(3) ?,α = 116.97(3),β = 94.08(3),γ = 103.29(3)o,V = 1280.2(4) ?3,Z = 1,C56H28Cl2F2N8O12Zn2,Mr = 1244.50,Dc = 1.614 g/cm3,F(000) = 628,μ(Mo Ka) = 1.124 mm-1,R = 0.0502 and w R = 0.1417.In compound 1,two 1,2,3-HBTC anions bridge two Zn(Ⅱ) atoms to give a dimeric structure with Zn···Zn distance of 3.15 ?.Adjacent dimers interact through π-π stackings between two L ligands to result in a supramolecular layer.Moreover,N–H···O and O–H···N hydrogen bonds further stabilize the 2D supramolecular architecture of 1.In addition,the luminescent property of 1 has been studied.
A new Zn (II) complex, [Zn (1,2,3-HBTC) (L)] 2 (1, L = 2- ] [1,10] phenanthroline and 1,2,3-H3 BTC = 1,2,3-benzentricarboxylic acid, was synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a = 10.455 (2), b = 11.533 (2), c = 12.499 (3) ?,? = 116.97 (3),? = 94.08 (3),? = 103.29 (3) o, V = 1280.2 4)? 3, Z = 1, C56H28Cl2F2N8O12Zn2, Mr = 1244.50, Dc = 1.614 g / cm3, F (000) = 628, Mo (Mo Ka) = 1.124 mm-1, R = 0.0502 and wR = 0.1417. compound 1, two 1,2,3-HBTC anions bridge two Zn (II) atoms to give a dimeric structure with Zn ··· Zn distance of 3.15 · .Adjacent dimers interact through π-π stackings between two L ligands to result in a supramolecular layer. Moreover, N-H ··· O and O-H ······ hydrogen bonds further stabilize the 2D supramolecular architecture of 1.In addition, the luminescent property of 1 has been studied.