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A new Zn-citrate coordination complex {K[Zn(C6H5O7)(H2O)]}n(1) was synthesized via hydrothermal reaction. In the crystal structure of complex 1, each citrate serves as the quadricdentate ligand coordinating to three Zn(II) ions, forming a zigzag chain, and such chains are further connected into a 3D network by the K+ linkers. Crystal data for complex 1: triclinic, space group P1, a = 7.3487(9), b = 7.5397(6), c = 9.6772(8) ?, α = 76.894(8), β = 68.260(10), γ = 65.155(10)°, V = 450.34(7) ?3 and Z = 2. Other characterizations by elemental analysis, IR, TG and fluorescence were also described.
A new Zn-citrate coordination complex {K [Zn (C 6 H 5 O 7) (H 2 O)]} n (1) was synthesized via hydrothermal reaction. In the crystal structure of complex 1, each citrate serves as the quadricdentate ligand coordinating to three Zn Crystal data for complex 1: triclinic, space group P1, a = 7.3487 (9), b = 7.5397 (6), c = 9.6772 (8), α = 76.894 (8), β = 68.260 (10), γ = 65.155 (10) °, V = 450.34 (7) -3 and Z = 2. Other characterizations by elemental analysis, TG and fluorescence were also described.