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The reactions of [PPh4][(η5-C5Me5)WS3] with four equiv of CuBr in DMF gave rise to a new cluster salt [Cu(DMF)6][(η5-C5Me5)WS3(CuBr)3]2·Et2O 1. The crystal structure of 1 (C42H76N6O7Br6Cu7S6W2, Mr = 2261.40) was determined by single-crystal X-ray dif