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Reaction of (NH 4) 2MoS 4 with [Cu(MeCN) 4](BF 4) and (n-Bu) 4NBr in CH 2Cl 2 afforded a new hexanuclear cluster [(n-Bu) 4N] 3[MoS 4Cu 5Br 6] (1). 1 crystallizes in the monoclinic system, space group P2 1/c, with lattice parameters a=1.17383(4) nm, b=2.40136(4) nm, c=2.64112(5) nm, β=94.2020(5)°, V=7.4247(5) nm 3 and Z=4. The structure of the [MoS 4Cu 5Br 6] 3- trianion of 1 is composed of one nido-like [MoS 3Cu 3] core and one half-open cubane-like [MoS 3Cu 3Br] core, which are interconnected by sharing the same MoSCuS plane. The Mo...Cu distances vary in the range of 0.2622(6)-0.2692(5) nm.
Reaction of (NH4) 2MoS4 with [Cu (MeCN) 4] (BF4) and (n-Bu) 4NBr in CH2Cl2 afforded a new hexanuclear cluster [(n-Bu) 4N] 3 [MoS4Cu 5Br6 1 crystallizes in the monoclinic system, space group P2 1 / c, with lattice parameters a = 1.17383 (4) nm, b = 2.40136 (4) nm, c = 2.64112 (5) nm, 5) °, V = 7.4247 (5) nm 3 and Z = 4. The structure of the [MoS 4Cu 5Br 6] 3- trianion of 1 is composed of one nido-like [MoS 3Cu 3] core and one half-open Cubane-like [MoS 3Cu 3Br] core, which are interconnected by sharing the same MoSCuS plane. The Mo ... Cu distances vary in the range of 0.2622 (6) -0.2692 (5) nm.