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由[Cu(MeCN)2 (PPh3)2 ](BF4 )和 4′ 苯基 2,2′:6′,2″ 三联吡啶(4′ Phtpy)在室温下反应,合成了一个新颖的具有光致发光性能的五配位配合物[Cu(4′ Phtpy)(PPh3)2 ](BF4 ).对配合物进行了X射线衍射结构表征,并进行了红外光谱、紫外可见光谱、荧光光谱等光谱学分析.晶体属单斜晶系,空间群Pn,晶胞参数:a =1 0 80 7(6)nm,b =1 0 943 (6)nm,c=2 1610(12 )nm,α =90°,β =10 2 785(10 )°,γ =90°,V =2 492(2 )nm3,Z =2,Dc=1 3 5 4g·cm-3.配合物中,Cu(Ⅰ)与 4′ Phtpy的 3个N,2个PPh3的P配位呈变形三角双锥型结构,其轴向由Cu键合联吡啶的末端 2个N所组成,赤道平面由联吡啶的中心N原子和 2个PPh3的P原子所组成
A novel phosphorescent photoreceptor was synthesized from [Cu (MeCN) 2 (PPh3) 2] (BF4) and 4 ’phenyl 2,2’: 6 ’, 2 "terpyridine (Cu (4 ’Phtpy) (PPh3) 2] (BF4) was synthesized and characterized by X-ray diffraction. The complexes were characterized by IR, UV-Vis and fluorescence spectroscopy The crystal belongs to the monoclinic system with the space group Pn and unit cell parameters: a = 1 0 80 7 (6) nm, b = 1 0 943 (6) nm, c = 2 1610 Cu (Ⅰ) and Cu (Ⅰ) were found to have a good solubility in water. The complex of Cu (Ⅰ) with β = 10 2 785 (10) °, γ = 90 ° and V = 2 492 (2) nm3 with Z = 2 and Dc = The 3-N and 2-PPh3 P-sites of 4 ’Phtpy showed a deformed triangular double conical structure. The axial direction of the 4’ Phtpy consisted of 2 N terminals of Cu-bonded bipyridyl. The equatorial plane consisted of the central N atom of bipyridine and Two PPh3 P atoms