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A new coordination polymer,[Ag(3,3-pybz)(3,3-Hpybz)]n(1,3,3-Hpybz=3-pyridin-3-yl-benzoic acid),has been synthesized and characterized by elemental analysis,IR spectra,PXRD,and single-crystal X-ray diffraction.In complex 1,the Ag(I)ions are linked by the paired3,3-pybz ligands to generate an infinite 1D loop chain,and further throughπ-πstacking interactions to form a 2D supramolecular architecture.Crystal data for 1:triclinic,space group P1,a=10.2635(17),b=10.3041(12),c=10.8060(13),V=1679.1(5)3,α=62.028(11),β=80.325(15),γ=78.738(14)°,Z=2,C24H17AgN2O4,Mr=505.27,Dc=1.698 g/cm3,μ=1.058 mm 1,F(000)=506,S=1.012 and T=293(2)K.The final R=0.0293 and wR=0.0667 for 3435 observed reflections with I>2σ(I),and R=0.0350 and wR=0.0688 for all data.
A new coordination polymer, [Ag (3,3-pybz) (3,3-Hpybz)] n (1,3,3-Hpybz = 3-pyridin-3-yl- benzoic acid), has been synthesized and characterized by elemental analysis, IR spectra, PXRD, and single-crystal X-ray diffraction in complex 1, the Ag (I) ions are linked by the paired3,3-pybz ligands to generate an infinite 1D loop chain, and further through π-π stacking interactions to form a 2D supramolecular architecture. Crystal data for 1: triclinic, space group P1, a = 10.2635 (17), b = 10.3041 (12), c = 10.8060 (13), V = 1679.1 62.028 (11), β = 80.325 (15), γ = 78.738 (14) °, Z = 2, C24H17AgN2O4, Mr = 505.27, Dc = 1.698 g / cm3, μ = 1.058 mm 1, F (000) = 506, S = 1.012 and T = 293 (2) K. The final R = 0.0293 and wR = 0.0667 for 3435 observed reflections with I> 2σ (I), and R = 0.0350 and wR = 0.0688 for all data.