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总结了ESI-MS在研究不对称催化反应上的应用,包括ESI-MS技术测定不对称催化反应产物ee值和ESI-MS技术表征不对称催化反应中的活性中间体/复合物,并进一步讨论了以此两种ESI-MS技术为基础的不对称反应对映选择性的评估和高通量手性催化剂筛选.
The application of ESI-MS in the study of asymmetric catalysis was summarized, including the determination of the ee value of asymmetric catalysis by ESI-MS and the characterization of reactive intermediates / complexes in asymmetric catalysis by ESI-MS The evaluation of asymmetric reaction enantioselectivity based on the two ESI-MS techniques and the screening of high-throughput chiral catalysts were performed.