新墨西哥大学(Albuquerque)的P.Enzel和T.Bein发明了一种在沸石型分子筛的孔系中合成导电性有机高聚物链的办法。分子筛先和金属离子[如铜(Ⅱ)]交换,后者可作为聚合反应中的氧化剂。在真空下使沸石孔失水,当沸石回至室温时,将气相或溶液中的单体引入沸石孔系中。Enzel等认为利用具有不同孔道拓扑性的沸石,可以达到控制在固体主体腔内 P. Enzel and T. Bein of the University of New Mexico (Albuquerque) invented a method of synthesizing conductive organic polymer chains in pore systems of zeolitic molecular sieves. Molecular sieves are exchanged first with metal ions [such as copper (II)], which act as an oxidizer in the polymerization. Zeolite pores are dehydrated under vacuum and when the zeolite is returned to room temperature, the monomers in the gas phase or solution are introduced into the zeolite pore system. Enzel and others believe that the use of zeolites with different pore topologies can be controlled within a solid body cavity