Rheological responses of fumed silica suspensions under steady and oscillatory shear

来源 :Science in China(Series E:Technological Sciences) | 被引量 : 0次 | 上传用户:longfushen
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Rheological experiments under steady and oscillatory shear were conducted for fumed silica suspen- sions in polyethylene glycol. Under steady shear the shear-thinning and thickening response were exhibited and the flow exponent N was determined. With the increase of concentration the flow exponent N showed a rapid increase, and it increased dramatically when the discontinuous shear-thickening took place. Oscillatory shear experiments were conducted at constant frequency and constant amplitude strain, respectively. The shear-thinning and the discontinuous shear-thickening behavior were observed under different constant frequencies from 10 to 80 rad/s. The correlation between complex modulus (G*) and sweep frequency (ω) was illuminated at γ =750%. It was found that the correlation between G* and ω could be fitted by equation: G*∝ωn. The indexes in shear-thinning region and shear-thickening were determined. The indexes were similar to some extent at shear-thinning region and increased dramati- cally to a much higher value when the shear-thickening occurred,especially at higher weight fractions. The behaviors can be qualitatively explained as follows: the shear-thinning owes to decrease of viscos- ity, which results from disruption of the aggregates; the cluster theory attributes the shear-thickening to the formation of metastable, flow induced clusters, which block the system. Rheological experiments under steady and oscillatory shear were conducted for fumed silica suspen-sions in polyethylene glycol. Under the steady shear the shear-thinning and thickening response were exhibited and the flow exponent N was determined. With the increase of concentration the flow exponent N showed a rapid increase, and it increased dramatically when the discontinuous shear-thickening took place. The shear-thinning and the discontinuous shear-thickening behavior were observed under different constant frequencies from 10 to 80 rad / s. The correlation between complex modulus (G *) and sweep frequency (ω) was illuminated at γ = 750%. It was found that the correlation between G * and ω could be fitted equation: G * αωn . The indexes in shear-thinning region and shear-thickening were determined. The indexes were similar to some extent at shear-thinning region and increas ed dramati- cally to a much higher value when the shear-thickening occurred, especially at higher weight fractions. The behaviors can be qualitatively explained as follows: the shear-thinning owes to decrease of viscos- ity, which results from disruption of the aggregates ; the cluster theory attributes the shear-thickening to the formation of metastable, flow induced clusters, which block the system.
其他文献
为配合建设部在全国推广钢结构技术应用的政策,适应全国钢结构的发展态势,特别是北京大规模的钢结构应用,中国钢铁工业协会、中国钢结构协会、中国贸促会冶金行业分会将继续
6月3日,波士顿咨询公司(BCG)发布的最新报告表示,在欧美日消费者信心一落千丈之时,中国消费者仍较为乐观。调查显示75%的消费者计划在未来一年内保持或增加消费,这一比例几乎
2009年,由甄子丹主演的一部经典电影《叶问》横空出世,其首日票房就高达1400万,超过了同期的另一部电影大片《梅兰芳》,短时间就在内地的票房破亿。而它在香港与新加坡的票房
改革开放以来,老区人民在党和政府的正确领导下,各方面取得了长足的进步和发展。从一穷二白到交通通信等基础设施的改善和老区人民生活水平的不断 Since the reform and ope
One new arsenic-vanadium cluster, [Zn(dien)(Hdien)]2[As6V15O42(H2O)]·4H2O (1, dien = diethylenetriamine), has been hydrothermally synthesized and characterized
一、引言离子束镀膜是利用从离子源引出的带能离子束,在无场的高真空(10~(-4)~10~(-5)托)环境中轰击所选择的靶材,溅射出二次原子,沉积在工件上成膜。离子束镀膜具有控制精确
Purpose: To investigate the effect of different intraocular lenses (IOLs) on lens epithelial cells (LECs) and on human capsular bags in vitro and to evaluate th
《上海国资》:作为上海中心城区的共性,长宁国资同样存在着“主业不突出,产业结构单一”等特点,《若干意见》出台后,区国资委如何推进主业战略、实现主辅分离?黄经麟:按照《
目的:运用PDCA循环法降低无纸化处方发药的差错隐患。方法:记录2013年1月~2013年12月杭州市中医院门诊实行无纸化处方发药前后的差错隐患事件以及原因,2014年1月~2014年6月运