论文部分内容阅读
A kinetics problem for a degrading polymer additive dissolved in a base stock is studied.The polymer degradation may be caused by the combination of such lubricant flow parameters aspressure, elongational strain rate, and temperature as well as lubricant viscosity and the polymercharacteristics (dissociation energy, bead radius, bond length, etc.). A fundamental approach tothe problem of modeling mechanically induced polymer degradation is proposed. The polymerdegradation is modeled on the basis of a kinetic equation for the density of the statistical distribu-tion of polymer molecules as a function of their molecular weight. The integrodifferential kineticequation for polymer degradation is solved numerically. The effects of pressure, elongational strainrate, temperature, and lubricant viscosity on the process of lubricant degradation are considered.The increase of pressure promotes fast degradation while the increase of temperature delaysdegradation. A comparison of a numerically calculated molecular weight distribution with an ex-perimental one obtained in bench tests showed that they are in excellent agreement with eachother.
A kinetics problem for a degrading polymer additive dissolved in a base stock is studied. The polymer degradation may be caused by the combination of such lubricant flow parameters as compressure, elongational strain rate, and temperature as well as lubricant viscosity and the polymer characteristics (dissociation energy, bead radius, bond length, etc.). A fundamental approach tothe problem of modeling mechanically induced polymer degradation is proposed. The polymer degradation is modeled on the basis of a kinetic equation for the density of the statistical distribu tion of polymer molecules as a function of their molecular weight. The integrodifferential kineticequation for polymer degradation is solved numerically. The effects of pressure, elongational strainrate, temperature, and lubricant viscosity on the process of lubricant degradation are considered. the increase of pressure promotes fast degradation while the increase of temperature delays degradation . A comparison of a numerically cal culated molecular weight distribution with an ex-perimental one obtained in bench tests showed that they are in excellent agreement with eachother.