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芳基溴、M4[Fe(CN)6](M=K,Na)、Na2CO3、Pd(OAc)2(0.1mol%~0.5mol%)于N,N-二甲基乙酰胺(DMAC)中,120℃反应1~5h,得到相应的芳腈,12例收率81%~96%。芳基溴的Pd(OAc)_2催化氰化反应@唐家邓
Aryl bromides in N, N-dimethylacetamide (DMAC) with M4 [Fe (CN) 6] (M = K, Na), Na2CO3 and Pd (OAc) 2 The reaction was carried out at 120 ℃ for 1 ~ 5h to obtain the corresponding aromatic nitrile. The yields of 12 were 81% ~ 96%. Aryl Bromine Pd (OAc) _2 Catalytic Cyanation @ Tangjia Deng