BN ceramic is an advanced engineering ceramics with excellent thermal shock resistance, good workability and excellent dielectricity.TiB 2 ceramic has excellent electric conductivity,high melting points, and corrosion resistance to molten metal.Therefore,the composite consisting of BN and TiB 2 ceramics is expected to have a combination of above mentioned properties,thereby can be used as self heating crucible.In this paper,hot pressing technology was used to fabricate the high performance BN TiB 2 composite materials.microstructure and electric conducting mechanism were studied,and the relationship between the microstructure and physical property was discussed.The results show that the microstructure of composites has a great influence on the physical property of composites.The BN TiB 2 composites with excellent mechanical strength and stable resistivity can be obtained by optimizing the processing parameter and controlling the microstructure of composites. BN ceramic is an advanced engineering ceramics with excellent thermal shock resistance, good workability and excellent dielectricity. Bi 2 ceramic has excellent electric conductivity, high melting points, and corrosion resistance to molten metal. Beforefore, the composite consisting of BN and TiB 2 ceramics is expected to have a combination of above mentioned properties, thus can be used as self heating crucible. In this paper, hot pressing technology was used to fabricate the high performance BN TiB 2 composite materials. microstructure and electric conducting mechanism were studied, and the relationship between the microstructure and physical property was discussed. The results show that the microstructure of composites has a great influence on the physical property of composites. The BN TiB 2 composites with excellent mechanical strength and stable resistivity can be obtained by optimizing the processing parameter and controlling the microstructure of composites.