Photolysis of oxygen saturated ethers in the presence of Sn(Ⅱ) or Cu(Ⅱ) salts

来源 :Chinese Journal of Chemistry | 被引量 : 0次 | 上传用户:boji13
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Photolysis of diethyl ether-oxygen charge transfer complex in the presence of Sn(Ⅱ)or Cu(Ⅱ)salts gave higher yields of the oxidation products,ethyl acetate,acetaldehyde,ethanol,ethyl formate and methanol compared with those without the salts.In addition,the photolysis of an oxygen saturated te-trahydrofuran(THF)or dibutyl ether solution gave y-butyro-lactone or butanol and butyl butyrate as major products with small amounts of undetermined compounds,respectively.Their yields were also affected by the addition of Cu(Ⅱ)or Sn(Ⅱ)salts. Photolysis of diethyl ether-oxygen charge transfer complex in the presence of Sn (II) or Cu (II) salts gave higher yields of the oxidation products, ethyl acetate, acetaldehyde, ethanol, ethyl formate and methanol compared with those without the salts. addition, the photolysis of an oxygen saturated te-trahydrofuran (THF) or dibutyl ether solution gave y-butyro-lactone or butanol and butyl butyrate as major products with small amounts of undetermined compounds, respectively.Their yields were also affected by the addition of Cu (Ⅱ) or Sn (Ⅱ) salts.
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