本文发展了一类新型的基于三蝶烯衍生大三环主体与质子化的2,2′-联吡啶盐/吡啶盐的主-客体体系.研究结果表明,大三环主体可以在溶液中和固态下与质子化的2,2′-联吡啶盐/吡啶盐形成1:2络合物,固态下络合物中两个客体以头尾交替的形式排列.研究还进一步实现了大三环主体与质子化的2,2′-联吡啶盐/吡啶盐络合与解络合过程的酸碱调控.另外,我们还设计合成了一个双吡啶盐客体,并通过其与大三环主体络合作用形成超分子聚准[3]轮烷组装体. In this paper, a new host-guest system based on triptorene-derived macrocycle and protonated 2,2’-bipyridyl / pyridinium salt has been developed.The results show that the main tricyclic ring can be neutralized in solution In the solid state, the protonated 2,2’-bipyridyl / pyridinium salt forms a 1: 2 complex, and the two guest complexes in the solid state are arranged alternately in a head-to-tail manner. The main body and the protonated 2,2’-dipyridyl / pyridinium salt complexation and the process of acid-base complexation.In addition, we also designed and synthesized a bispyridinium salt object, and through its main tricyclic ring network Cooperate to form supramolecular polyatomic [3] rotaxane assembly.