【摘 要】
：
Two new inclusion compounds (n-C4H9)4N+C18-pared and characterized by X-ray crystallography.Crystal data:compound 1,monoclinic P2(1)/c,a = 1.569 9(1) nm,b = 0.9
【机 构】
：
College of Chemistry,Beijing Normal University,Beijing 100875,China“,”School of Chemical Biology and
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Two new inclusion compounds (n-C4H9)4N+C18-pared and characterized by X-ray crystallography.Crystal data:compound 1,monoclinic P2(1)/c,a = 1.569 9(1) nm,b = 0.995 5(6) nm,c = 2.293 3(1) nm,β = 109.962(3)°,Z=4,and R1 = 0.0434,wR = 0.075 9;compound 2,monoclinic C2/c,a = 1:400 5(3)nm,b = 1.282 1(2) nm,c = 1.765 7(3) nm,β = 100.388(1)°,Z = 4,and R1 = 0.0584,wR = 0.096 6.In the crystal structure of 1,the tetramers formed by two trans-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylic acid (EADA) anions and two boric bonds to generate a channel type host lattice.The tetra-n-butylammonium cations were stacked to give two columns within each channel with cross-sectional size of about 2.30 nm × 0.93 nm.In the crystal structure of 2,similar honeycomb host lattices with big size were also formed along the [101] direction by three-dimensional accumulation of EADA anions.The tetra-n-butylammonium cations were accommodated in a zigzag fashion within each channel.
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