,A Novel Efficient Red Emitting Iridium Complex for Polymer Light Emitting Diodes

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Photo-physical properties of iridium complexes bis(1-(2,4-difluorobiphenyl-4-yl)isoquinoline)iridium(Ⅲ)(5-(4-(bis(4-methoxyphenyl)amino)phenyl)picolinic acid) used as phosphorescent dopant in polymer light-emitting devices with a blend of poly(9,9-dioctylfluorene) and 2-tert-butyl-phenyl-5-biphenyl-1,3,4-oxadiazole as a host matrix are investigated.The iridium complex exhibits distinct UV-vis absorption bands around 300 450 nm and intense red photoluminescent emissions peaked at around 618nm in dichloromethane.The devices display a maximum exteal quantum efficiency of 4.8% and luminous efficiency of 3.1 cd·A-1 at current density of 3.2mA·cm-2 with a dominant red emission peak around 620nm and a shoulder around 660nm.At 100mA·cm-2,the devices still display a maximum exteal quantum efficiency as high as 3.9%.
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