论文部分内容阅读
A new class of rhodium complexes with high catalytic activity as well as excellent stability,which was used as catalyst for carbonylation of methanol to acetic acid,is reported.It contains free donor (namely un-coordinated donor) atoms which enable to improve its stability by intramolecular substitution reaction.Its synthesis,characteristic and catalytic reaction were discussed here.
A new class of rhodium complexes with high catalytic activity as well as excellent stability, which was used as catalyst for carbonylation of methanol to acetic acid, is reported. It contains free donor (ie un-coordinated donor) atoms which enable to improve its stability by intramolecular substitution reaction. Its synthesis, characteristic and catalytic reaction were discussed here.