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A new μ-chloro-bridged one-dimensional coordination polymer Cd(dmbpy)Cl2n(dmbpy=4,4′-dimethyl-2,2′-bipyridine) has been synthesized and structurally characterized by elemental analyses=IR=UV spectra and single-crystal X-ray diffraction.The complex crystallizes in the monoclinic system=space group C2/c with a=17.745(4)=b=10.326(2)=c=7.3382(15)=β=106.85(3)o=V=1286.9(4)3=Z=4=C12H12N2Cl2Cd=Mr=367.54=Dc=1.897 g/cm3=F(000)=720=λ(MoKα)=0.71073=μ=2.089 mm-1=R=0.0368 and wR=0.1048 for 1041 observed reflections(I > 2σ(I)).Cadmium(II) adopts a distorted octahedral coordination geometry and adjacent coordination chains are intercalated in a zipper-like fashion into 2D layers through the π-π stacking interactions between dmbpy.Fluorescent
A new μ-chloro-bridged one-dimensional coordination polymer Cd (dmbpy) Cl2n (dmbpy = 4,4’-dimethyl- 2,2’-bipyridine) has been synthesized and structurally characterized by elemental analyzes = IR = UV spectra and single -crystal X-ray diffraction. The complex crystallizes in the monoclinic system = space group C2 / c with a = 17.745 (4) = b = 10.326 (2) = c = 7.3382 = β = 106.85 (3) o = V = 1286.9 (4) 3 = Z = 4 = C12H12N2Cl2Cd = Mr = 367.54 = Dc = 1.897 g / cm3 = F (000) = 720 = λ (MoKα) = 0.71073 = μ = 2.089 mm -1 = R = 0.0368 and wR = 0.1048 for 1041 observed reflections (I> 2σ (I)). Cadmium (II) adopts a distorted octahedral coordination geometry and adjacent coordination chains are intercalated in a zipper-like fashion into 2D layers through the π-π stacking interactions between dmbpy.Fluorescent