近年来,由高聚物配体与过渡金属配位而成的所谓高分子催化剂的研究十分活跃,对由高聚物中不同配位原子与不同金属按不同配比(如M/N、M/P、M/O等)制成的配合物的性能有详细报道。配合物所含配键的差异,已直接反映着催化剂的性能,而含有两种以上配位原子的共聚物与金属形成的催化剂在性能上有其显著的特点。研究结果证明,这类配合物所 In recent years, polymer ligands and transition metal coordination made from the so-called polymer catalyst is very active, the polymer by different coordination atoms with different metals at different ratios (such as M / N, M / P, M / O, etc.) made of the complex properties are reported in detail. The difference of the coordination bonds contained in the complex has directly reflected the performance of the catalyst. However, the performance of the catalyst formed by the copolymer and the metal containing two or more coordination atoms has remarkable characteristics. The results show that these complexes