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A novel bis (phenoxo) bridged binuclear copper ( II) complex with dissimilar coordination environments was synthesized and characterized by spectroscopies and X-ray crystallography. It crystallized in the monoclinic system with space group C2/c, a=2. 241 1(2) nm, b=1. 834 2 (2) nm, c=1.877 9(2) nm, β=122.861(2)°, V=6.484 3(11) nm3, Z=8. Itconsistsof two unsymmetrical Cu (Ⅱ ) centers bridged by two phenolic oxygen atoms to yield a Cu2O2 core with the Cu-Cu separation of 0. 310 2 nm, in which Cul and Cu2 ions exhibit distorted N2O3 and N3O2 square pyramidal geometries, respectively.
A novel bis (phenoxo) bridged binuclear copper (II) complex with dissimilar coordination environments was synthesized and characterized by spectroscopies and X-ray crystallography. It crystallized in the monoclinic system with space group C2 / c, a = 2. 241 (2) nm, β = 122.861 (2) °, V = 6.484 3 (11) nm3, Z = 8. Itconsistsof two unsymmetrical Cu (Ⅱ) ) centers bridged by two phenolic oxygen atoms to yield a Cu2O2 core with the Cu-Cu separation of 0. 310 2 nm, in which Cul and Cu2 ions exhibit distorted N2O3 and N3O2 square pyramidal geometries, respectively.