【摘 要】
:
Octaphenylsilsesquioxane(OPhS) was prepared by a modifying method and a new core-shell nanocomposite, octa(2,4-dinitrophenyl)silsesquioxane, [(R2PhSiO1.5)8, R=-
【机 构】
:
Department of Chemistry
论文部分内容阅读
Octaphenylsilsesquioxane(OPhS) was prepared by a modifying method and a new core-shell nanocomposite, octa(2,4-dinitrophenyl)silsesquioxane, [(R2PhSiO1.5)8, R=-NO2, ODNPhS], was synthesized by nitration of OPhS in a mixed acid solution of nitric and sulfuric acids at about 60 ℃. Their molecular structures were determined by DRIFTS, 1H NMR, 13C NMR spectra analysis. The thermal analysis shows that ODNPhS is an explosive that detonates at about 420 ℃.
其他文献
A novel coordinated complex [(5-nitrophen)Pd(CF3CO2)2] (5-nitrophen = 5-nitro-l,10-phenanthroline) was first synthesized. By using XPS, IR, and 1H-NMR, its coor
A system for the numerical simulation of 3D temperature and stress fields during casting process was studied, developed and practiced based on finite differenc
Some chiral binaphthyl crown ethers were synthesized. The anionic polymerization of methyl methacrylate (MMA) was carried out in the presence of t-BuOK, Ph2CHK
Here the authors are interested in the zero set of Sobolev functions and functions of bounded variation with negative power of integrability. The main result is
A series of monometallic nitrides and bimetallic nitrides were prepared by temperature-programmed reaction with NH3. The effects of Co, Ni and Fe additives and
The cellular neural/nonlinear network (CNN) is a powerful tool for image and video signal processing,robotic and biological visions. This paper discusses a gene
The synthesis of a new type of polymers with main chain chirality based on BINOL skeleton is described. Titanium-BINOLate catalysts are easily generated from th
Trial function method is applied to solve generalized mKdV (GmKdV for short) equations. It is shown that GmKdV equations with a realnumber parameter can be solv
The title complex NiL(py)3, where H2L = N-salicylaldehyde-N'-phenoxyacetyl hydrazine, was prepared and characterized by X-ray diffraction. The single crystal of
The experimental investigation demonstrates that a satisfactory result can be expected for pressure swing adsorption (PSA) purification of natural gas as raw ma