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碘（溴）醇类衍生物的制备ＭａｓｕｄａＨ等［ＪＯｒｇＣｈｅｍ１９９４；５９：５５５０］Ｈ５ＩＯ６（或ＮａＢｒＯ３）在ＮａｎＳＯ３存在下生成次卤酸ＩＯＨ（或ＢｒＯＨ），可与Ｃ＝Ｃ化合物发生原位加成。生成碘（溴）醇类化合物。对链内烯烃，碘羟基化具有较高的立...
Preparation of iodo (bromo) alcohol derivatives MasudaH et al. [JOrg Chem. 1994; 59: 5550] H5IO6 (or NaBrO3) generates hypohalous acid IOH (or BrOH) in the presence of NanSO3 and can undergo in situ addition to the C = C compound. Produce iodine (bromine) alcohol compounds. On the chain of olefins, iodine hydroxylation has a higher ...