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合成了第Ⅷ族元素的均相催化剂和膦化的聚苯乙烯树脂键联的载体化催化剂。用于环十二碳三烯选择加氢反应,评选出了均相和载体化钌膦络合物催化剂;研究了它们的反应较佳条件,考察了载体化催化剂的寿命。
A homogeneous catalyst of a Group VIII element was synthesized with a phosphonated polystyrene resin-linked supported catalyst. For the selective hydrogenation of cyclododecatriene, the homogeneous and supported ruthenium-phosphine complex catalysts were selected. The optimum conditions for their reaction were investigated, and the life of the supported catalyst was investigated.