论文部分内容阅读
本文报道了(N,N-二乙基)胺甲基二茂铁钯配合物的合成及其与烯烃的反应,以及(N,N-二乙基)胺甲基二茂铁(Ⅰ)、钯配合物(Ⅱ)和反应产物的波谱性质。 1 实验 1.1 仪器 IR光谱用Shimadzu IR-450红外分光光度计测定,固体用KBr压片,液体用CsI涂片。Ⅰ和反应产物的~1H NMR谱用Varian EM-390核磁共振仪测定,氘代氯仿作溶剂;Ⅱ用Varian XL-200核磁共振仪测定;氘代二甲亚砜作溶剂。均以TMS作内标。
This paper reports the synthesis of (N, N-diethyl) amine methylferrocene palladium complex and its reaction with olefins, and the reaction of (N, N-diethyl) aminomethylferrocene Spectroscopic Properties of Palladium Complex (Ⅱ) and Reaction Products. 1 Experiment 1.1 The instrument IR spectra were measured on a Shimadzu IR-450 infrared spectrophotometer. The solid was KBr pressed and the liquid was smeared with CsI. The ~ 1H NMR spectra of I and the reaction products were determined using a Varian EM-390 nuclear magnetic resonance spectrometer with deuterated chloroform as the solvent; II with a Varian XL-200 nuclear magnetic resonance spectrometer; and deuterated dimethyl sulfoxide as the solvent. TMS for internal standards.