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报导了以红外光谱表征油田勘探开发用聚合物结构、组成的部分研究结果,分析了TM,P(AM-TM),CPVP的分子结构,结合C13NMR确认了CPVP的原料与产物对位结构形态;提出了以不干挠特征谱带面积比测算AM-AN共聚物中AN含量的方法;探讨了粘土自身的基团相互作用和聚合物与粘土的相互作用。
The results of some studies on the structure and composition of oilfield exploration and development polymers by infrared spectroscopy were reported. The molecular structures of TM, P (AM-TM) and CPVP were analyzed. The para structure of CPVP was confirmed by C13 NMR. The method to calculate the AN content in AM-AN copolymer by non-flexible characteristic band area ratio was discussed. The interaction of clay with itself and the interaction between polymer and clay were also discussed.