Towards efficient near-infrared fluorescent organic light-emitting diodes

来源 :光:科学与应用(英文版) | 被引量 : 0次 | 上传用户:macrosoft
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The energy gap law (EG-law) and aggregation quenching are the main limitations to overcome in the design of near-infrared (NIR) organic emitters. Here, we achieve unprecedented results by synergistically addressing both of these limitations. First, we propose porphyrin oligomers with increasing length to attenuate the effects of the EG-law by suppressing the non-radiative rate growth, and to increase the radiative rate via enhancement of the oscillator strength. Second, we design side chains to suppress aggregation quenching. We find that the logarithmic rate of variation in the non-radiative rate vs. EG is suppressed by an order of magnitude with respect to previous studies, and we complement this breakthrough by demonstrating organic light-emitting diodes with an average external quantum efficiency of~1.1%, which is very promising for a heavy-metal-free 850 nm emitter. We also present a novel quantitative model of the internal quantum efficiency for active layers supporting triplet-to-singlet conversion. These results provide a general strategy for designing high-luminance NIR emitters.
其他文献
为进一步加深对压气机静子角区分离流动非定常性和湍流特性的认识,以某台用于低速模拟的多级低速轴流压气机的第3级改型静子为研究对象,采用延迟脱落涡模拟(DDES)方法进行详
采用大涡模拟方法对紧凑式强预冷换热器叉排管束的对流换热问题进行了研究,并运用动力模态分解(DMD)方法对流场的拟序结构及换热统计特性进行了分析.结果表明:在计算工况内(R
为探究不同磨损影响因素对浮动花键磨损的影响程度,基于能量耗散理论,建立了花键副微动磨损预测模型,分析了扭矩、载荷波动、花键材料、摩擦因数、轴向不对中以及角向偏心对
针对仅以评价准确性为目标的多超声评价方法易失去单调可评价性这一问题,同时以准确性、单调性为优化目标,提出一种面向GH4169晶粒尺寸的双目标多超声参数评价方法.根据相关
为了明确采用高负荷设计及一般设计(低负荷)方法的压气机气动性能和流动转捩的差异,进行了不同攻角下的叶栅吸力面流谱绘制和参数测量实验.并基于实验边界条件,采用γ-θ转捩
为开展气流激励下叶片振动响应分析方法研究,建立了气动激振力预估方法,采用非线性谐波法对叶排进行三维非定常流动分析,获得叶片表面的脉动压力,编制流固转换程序,计算叶片
Optical coherence tomography (OCT) has become one of the most important techniques in ophthalmic diagnostics, as it is the only way to three-dimensionally visua
期刊
为研究温度冲击载荷对某改性双基推进剂装药结构完整性的影响,基于热力耦合基本理论,开展了不同温度下改性双基推进剂力学松弛试验,得到了不同温度下松弛模量的6阶Prony级数
提出了一种基于翼型前缘范围流场相似的多控制点混合缩比翼型优化设计方法:以前缘局部范围内的空间流场特征相同为目标,采用多目标遗传优化算法结合翼型参数化、多控制点、网
采用中位数估计和Huber M估计相融合方法对未知分布的时间序列数据进行稳健处理,得到时间序列稳健数据,进一步得到时间序列数据的本征区间、变异率、中位数和平均值,组成时间