Construction of ternary CuO/CuFe2O4/g-C3N4 composite and its enhanced photocatalytic degradation of

来源 :环境科学学报(英文版) | 被引量 : 0次 | 上传用户:qiaoweizhuo
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
In this study,a graphitic carbon nitride (g-C3N4) based ternary catalyst CuO/CuFe2O4/g-C3N4 (CCCN) is successfully prepared thorough calcination method.After confirming the structure and composition of CCCN,the as-synthesized composites are utilized to activate persulfate (PS) for the degradation of organic contaminant.While using tetracycline hy-drochloride (TC) as pollutant surrogate,the effects of initial pH,PS and catalyst concen-tration on the degradation rate are systematically studied.Under the optimized reaction condition,CCCN/PS is able to give 99% degradation extent and 74% chemical oxygen de-mand removal in assistance of simulated solar light,both of which are apparently greater than that of either CuO/CuFe2O4 and pristine g-C3N4.The great improvement in degradation can be assignable to the effective separation of photoinduced carriers thanks to the integra-tion between CuO/CuFe2O4 and g-C3N4,as well as the increased reaction sites given by the g-C3N4 substrate.Moreover,the scavenging trials imply that the major oxidative matters involved in the decomposition are hydroxyl radicals (·OH),superoxide radicals (·O2-) and photo-induced holes (h+).
其他文献
We present the continuously measurements of volatile organic compounds (VOCs) at a re-ceptor site (Wan Qing Sha,WQS) in the Pearl River Delta (PRD) region from September to November of 2017.The average mixing ratios of total VOCs (TVOCs) was 36.34± 27.9 p
Urban black blooms that are primarily caused by organic carbon are deleterious environ-mental problems.However,detailed studies on the microbial characteristics that form ur-ban black blooms are lacking.In this study,we observed the composition,diversity,
The recycling reverse osmosis (RO) membrane concentrate of some high-ammonia nitrogen(NH4+-N) organic wastewater to the biological unit could cause potassium ion (K+) accumu-lation,thereby affecting the removal of NH4+-N by activated sludge.Thus,the effec
In this study,complete tetracycline (TTC) and above 50% of total organic carbon (TOC) were removed by FeS/PS after 30 min under optimized conditions.Although free radicals and high-valent iron ions were identified to generate in the process,the apparent s
Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous priority pollutants that cause great damage to the natural environment and health.Average genome size in a community is critical for shedding light on microbiome\'s functional response to pollution
Pyrethroids,organophosphorus pesticides and fipronil have been listed as priority chemi-cals in human biomonitoring studies because of their wide use and potential health effects in humans.The determination of 13 pesticides,including pyrethroids (deltamet
Nonylphenol (NP) residues,as a typical endocrine disrupting chemical (EDC),frequently exist in sewage,surface water,groundwater and even drinking water,which poses a se-rious threat to human health due to its bioaccumulation.In order to remove NP,a series
Black carbon (BC) plays an important role in air quality and climate change,which is closely associated with its mixing state and chemical compositions.In this work the mixing state of BC-containing single particles was investigated to explore the evoluti
The aim of this study is to investigate conversion of nitrogen and COD in enriched paddy soil by nitrification coupled with anammox process in a dual chamber bioelectrochemical system.The paddy soil was enriched for denitrification coupled with anammox by
Biomass fermentation provides a potential route toward the ecological disposal for the bauxite residue (BR) with high alkalinity issues.However,how to accelerate the remedia-tion of the alkaline problem with a long-term durability is still a big challenge