The microstructure, friction and wear behaviour of graphite preform and graphite/antimony composites are analysed based on the percolation theory of hydrodynamics to investigate the relationship between the percolation net- work and physical properties of graphite/antimony composites. The result shows that there are two important factors to enhance friction and wear behaviour of graphite/antimony composites at high temperature: 1) the formation of the pore network in the preform, which is called the first percolation and 2) the optimization of infiltration method in the process of infiltrating antimony, which is called the second percolation. By adding some pyrolysate and controlling the roasting process, perfect net pores and sub-micron percolation microstructure may be formed in the graphite preform. By con- trolling the infiltration process, the saturation of molten antimony infiltrating into perfect pores can be optimized. The microstructure, friction and wear behavior of graphite preform and graphite / antimony composites are analysed based on the percolation theory of hydrodynamics to investigate the relationship between the percolation net-work and physical properties of graphite / antimony composites. The result shows that there are two important factors to enhance friction and wear behavior of graphite / antimony composites at high temperature: 1) the formation of the pore network in the preform, which is called the first percolation and 2) the optimization of infiltration method in the process of infiltrating antimony, which is called the second percolation. By adding the pyrolysate and controlling the roasting process, perfect net pores and sub-micron percolation microstructures may be formed in the graphite preform. By controlling the infiltration process, the saturation of molten antimony infiltrating into perfect pores can be optimized.