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The mixed-quadriligand bismuth complex [Bi(S2CNEt2)2(NO3)]?[1,10-Phen] has been synthesized, and its crystal structure was determined by X-ray single-crystal diffraction. The crystal belongs to monoclinic, space group P21/n with a = 10.074(17), b = 15.05(2), c = 18.99(3) ?, β = 98.85(3)o, V = 2845(8) ?3, Z = 4, F(000) = 1464, Dc = 1.746 g/cm3, μ = 6.523 mm-1, R = 0.0333 and wR = 0.0703. In this complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry.
The mixed-quadriligand bismuth complex [Bi (S2CNEt2) 2 (NO3)] [1,10-Phen] has been synthesized, and its crystal structure was determined by X-ray single-crystal diffraction. The crystal belongs to monoclinic, space group P21 / n with a = 10.074 (17), b = 15.05 (2), c = 18.99 (3) ?,? = 98.85 (3) o, V = 2845 (8)? 3, Z = 4, F 000) = 1464, Dc = 1.746 g / cm3, μ = 6.523 mm-1, R = 0.0333 and wR = 0.0703 In this complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry.