论文部分内容阅读
醛或酮与甲脒阴离子发生增碳反应生成腈[Santia-goBetal.TetrahedronLett,1993;34:5839]羰基化合物与2-三甲基硅甲基甲脒的阴离子反应生成烯脒中间体,后者可转化为增加一个碳原子的氰基化合物,其中从2-乙酰-6-个甲...
The aldehydes or ketones react with carboxamidine anion to form nitrile [Santia-go et al. Tetrahedron Lett, 1993; 34: 5839] The carbonyl compound reacts with the anion of 2-trimethylsilylmethyl formamidine to form the ene amidine intermediate, which can be converted to a cyano compound with one additional carbon atom, 6-A